APS22 Hydrofluoric Acid-Resistant pH Electrode

The ARTang APS22 is designed for online pH measurement in aqueous process liquids containing hydrofluoric acid. The maximum stated hydrofluoric acid concentration is up to 4000 ppm under confirmed process conditions.

The APS22 is suitable for selected semiconductor wastewater, metal-treatment processes, electronics and electroplating wastewater, steel-industry effluent and other diluted HF-containing aqueous streams.

  • Measurement range: 0~14 pH
  • Maximum stated HF concentration: up to 4000 ppm
  • Operating temperature: 0–100°C
  • Operating pressure: 0–3 bar
  • Standard PG13.5 process connection
  • Multiple insertion lengths and connector options
  • IP68 for applicable sealed configurations

    Product Description

    The APS22 uses a specialized HF-resistant glass, an HF-service GFT gel electrolyte, and a double-junction design. Combined with a multi-pore ceramic junction and optional configurations, it offers improved resistance in hydrofluoric acid media while maintaining stable pH measurement performance.

    Multiple insertion lengths, temperature elements and electrical connectors are available for new installations, OEM systems and replacement projects.

    Technical Specifications

    Parameter

    Specification

    Product model

    APS22

    Product type

    Hydrofluoric acid-resistant industrial pH electrode

    Measurement range

    0~14 pH

    Maximum stated HF concentration

    Up to 4000 ppm under confirmed operating conditions

    Operating temperature

    0~100°C

    Operating pressure

    0~3 bar

    Zero point

    pH 7.00 ±0.25

    Process connection

    PG13.5

    Protection rating

    IP68 for applicable correctly sealed configurations

    Insertion length

    120, 150, 225, 325 or 425 mm

    Temperature element

    NTC 10K, NTC 2.252K, NTC 22K, Pt100 or Pt1000

    Electrical connector

    S8, S8M, S7, VP, K8S or K2

    Key Features and Engineering Benefits

    APS22 HF-resistant pH electrode for diluted hydrofluoric acid applications up to 4000 ppm
    APS22 pH electrode with double-junction reference, mixed-gel electrolyte and multi-pore ceramic junction

    Specialized HF-Resistant Glass Membrane

    Provides improved resistance to HF-related membrane etching compared with conventional pH glass, helping reduce premature drift and sensor failure under confirmed conditions.

    Maximum Stated HF Concentration up to 4000 ppm

    Supports online pH measurement in diluted HF process liquids, rinse water and fluoride-bearing industrial wastewater where a standard glass electrode may have an unacceptably short service life.

    Double-Junction Reference Construction

    HF-Service GFT Mixed-Gel Electrolyte

    Special Multi-Pore Ceramic Junction

    Optional Junction Configurations

    Multiple Temperature Element Options

    NTC 10K / NTC 2.252K / NTC 22K / Pt100 / Pt1000

    Standard PG13.5 Connection

    Typical Applications

    Metal Surface Treatment

    • Diluted acid etching rinse water
    • Metal-surface treatment wastewater
    • HF-containing cleaning wastewater
    • Neutralization tanks
    • Fluoride precipitation processes
    • Treated-effluent monitoring

    Electronics and Electroplating

    • Electronics manufacturing wastewater
    • Electroplating wastewater
    • Surface preparation rinse water
    • Fluoride-bearing wastewater treatment
    • Acid and alkali neutralization systems

    Steel Industry Wastewater

    • Selected acid-pickling wastewater
    • Steel-surface treatment effluent
    • Diluted HF-containing rinse water
    • Waste-acid neutralization processes
    • Fluoride removal and precipitation systems

    Semiconductor and Electronics Wastewater

    • Semiconductor etching rinse wastewater
    • Wafer-cleaning wastewater
    • Fluoride-bearing process wastewater
    • Scrubber water containing diluted HF
    • HF wastewater collection tanks
    • Neutralization and fluoride-removal processes

    OEM Wastewater-Treatment Equipment

    • HF wastewater-treatment skids
    • Fluoride-removal systems
    • Neutralization equipment
    • pH adjustment panels
    • Industrial water-quality monitoring systems
    • OEM chemical-treatment equipment

    FAQ

    Does 4000 ppm refer to free HF or total fluoride?

    The 4000 ppm value refers to hydrofluoric acid (HF) concentration, not total fluoride. 

    Is the HF-resistant glass completely immune to hydrofluoric acid?

    No.

    The specialized glass provides improved resistance compared with conventional pH glass, but HF can still attack it. Higher HF concentration, lower pH, higher temperature and longer exposure generally increase the rate of glass degradation.

    Why can’t a standard glass pH electrode be used in HF?

    Hydrofluoric acid reacts with the silica structure of conventional pH glass.

    This can cause:

    • Membrane etching
    • Measurement drift
    • Slow response
    • Reduced slope
    • Thinning of the sensing membrane
    • Premature breakage
    • Shortened electrode life
    Can the APS22 replace another PG13.5 pH electrode?

    Possibly, but PG13.5 thread compatibility alone is not sufficient.

    Also confirm:

    • Electrode length
    • Insertion depth
    • Connector type
    • Temperature element
    • Cable configuration
    • Transmitter input
    • Process pressure
    • HF compatibility
    Can the junction and electrolyte be customized?

    Yes.

    Available customization includes:

    • Two-point or three-point ceramic junctions
    • Annular porous PTFE junction
    • Application-specific reference electrolyte
    • Multiple insertion lengths
    • Temperature-element options
    • Connector configurations

    Request a Quote and HF Compatibility Review

    Need an APS22 quotation or confirmation for an HF-containing process?

    Send us your free HF concentration, total fluoride, pH, temperature, pressure, complete chemical composition, installation method, insertion length, temperature element and connector requirements.

    ARTang will review the process conditions and confirm whether the APS22 is suitable before quotation.

    Factory Strength & Quality Assurance

    ARTang supports industrial measurement projects with in-house production, strict calibration, certified quality control, and global exhibition experience.

    Factory Production

    In-house production and assembly for stable product quality and reliable delivery.

    Worker operating production equipment for instruments and meters

    CNC Machining Equipment

    ARTang worker operating production instruments and equipment

    Product Assembly

    CNC Machining

    Welding Process

    artang warehouse

    warehouse

    Technical Support Department

    Certified Quality

    Product certificates and quality control systems support reliable industrial measurement applications.

    CE certificate for electromagnetic flowmeter

    CE

    ISO 9001 quality management system certificate

    ISO

    3-A sanitary certificate for electromagnetic flowmeter

    3-A

    NEPSI explosion protection certificate for integral magnetic flowmeter

    NEPSI

    Exhibition Experience

    ARTang meets customers and distributors at industry exhibitions to better understand project needs and market requirements.

    ARTang at an industrial instrumentation exhibition, showcasing flow meters and pressure transmitters for process automation applications